I don't use a cart for golf, however based on the one time I did, the bottom of the bag would sit toward the back of the cart seat to enable access to pockets, ball silo etc. If that's the case the putter would be the first accessible club, followed by the wall of woods and then irons and finally wedges. The back of the cart seat would be at the bottom of the above photo.
On a trolley, the setup above would have the trolley underneath the wedges and the putter uppermost. Possibly a better trolley setup than cart setup.
I also received an incorrect and not fantastically useful reply from Ogio:
Thank you for contact Ogio. As with any top you can arrange your clubs to our liking but the suggest way would be the woods on one side and the irons on the other.
Sides? What sides?
One other strange thing on the bag is that the loading handle is underneath it, not on top. Probably a good reason for it but it's worth mentioning as it means having to use the carry strap to unload/load in and out of the car and (for me!) renders the loading handle useless. If I used the loading handle, all my clubs would spin around and clatter into each other, to then be spin back around and clatter into each other again when put on the trolley. May be different for cart users.